2-(3-Bromo-4-methoxyphenyl)-3-nitropyridine

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5-Benzoylamino-3-bromo-4-(4-methoxyphenyl)-4,5-dihydroisoxazole-5-carboxylic acid.

The title compound, C18H15BrN2O5, a promising N-protected alpha-amino acid, was synthesized directly from an unusual bromo dipole and a 4-(arylmethylene)oxazolone. The crystal packing of the title compound is a racemic mixture. Peculiar graph-set motifs driven by the most important hydrogen bonds are described.

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Methyl 2-bromo-3-(4-chloro­benzene­sulfonamido)­benzoate

In the crystal structure of the title compound, C(14)H(11)BrClNO(4)S, the mol-ecules form inversion dimers with R(2) (2)(8) motifs through pairs of N-H⋯O hydrogen bonds. The benzene rings are not coplanar and subtend a dihedral angle of 66.27 (8)°. The carbomethoxy group makes a dihedral angle of 75.1 (1)° with the ring to which it is attached.

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4-Bromo-3-hy­droxy-3-(4-hy­droxy-2-oxo-2H-chromen-3-yl)indolin-2-one

In the mol-ecule of the title compound, C(17)H(10)BrNO(5), the indoline system and the attached coumarin ring are each essentially planar with maximum deviations of 0.074 (2) and 0.062 (2) Å, respectively. The dihedral angle between them is 85.09 (3)°. In the crystal, all heteroatoms (except for the coumarin oxo O atoms) are involved in intra- and inter-molecular hydrogen bonds. An intra-molecu...

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2-(3-Bromo-4-meth­oxy­phen­yl)acetic acid

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(E)-4-Bromo-N-{(E)-3-[(4-bromo-2-methyl­phen­yl)imino]­butan-2-yl­idene}-2-methyl­aniline

The title compound, C(18)H(18)Br(2)N(2), is centrosymmetric with the mid-point of the central C-C bond of the butyl group located on an inversion center. The terminal benzene ring is approximately perpendicular to the central butyl plane [dihedral angle = 71.9 (8)°]. No hydrogen bonding or aromatic stacking is observed in the crystal.

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ژورنال

عنوان ژورنال: IUCrData

سال: 2017

ISSN: 2414-3146

DOI: 10.1107/s2414314617013943